Vol 7, No 3 (2016) > Metalurgy and Material Engineering >

Kappa-Carrageenan as an Attractive Green Substitute for Polyacrylamide in Enhanced Oil Recovery Applications

Made Ganesh Darmayanti, Cynthia Linaya Radiman, I Made Sudarma

 

Abstract:

The rapidly growing demand for petroleum resources has become a crucial
global problem. Therefore, a more realistic solution is required for oil
production. Enhanced oil recovery (EOR) has become an essential technique to
extract original oil content and maintain oil fields. During this process,
certain viscous polymers are commonly used as mobility control agents. In this
work, we introduce a new class of polymer to address the limitations of
commercial EOR polymers. We successfully extracted kappa-type carrageenan from Eucheuma
cottonii
seaweed using demineralized water and ethanol precipitation. The
amount of yield, intrinsic viscosity, and viscosity-average molecular mass of
the extracted carrageenan were 18.64%, 12.77 dLg-1, and 4.716×105
gmol-1, respectively. Characterizations were done by dynamic
viscosity and rheological measurement, along with a thermal degradation test.
The measurements indicated that kappa-carrageenan
is an attractive green substitute for polyacrylamide, as it showed relatively
high resistance to temperature, shear rate, and salinity compared to
polyacrylamide-based commercial EOR polymers. However, a higher concentration
of carrageenan is still needed to reach the same viscosity as the commercial
polymers.

Keywords: Eucheuma cottonii; Kappa-carrageenan; Enhanced oil recovery; Rheological measurement

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References


Alvarado, V., Manrique, E., 2010. Enhanced Oil Recovery Field Planning and Development Strategies. Elsevier Inc., USA

Bhattacaharyya, S., Tobacman, J.K., 2012. Molecular Signature of Kappa-carrageenan Mimics Chondroitin-4-sulfate and Dermatan Sulfate and Enables Interactions with Aryl Sulfatase B. Journal of Nutritional Biochemistry, Volume 23, pp. 1058–1063

Darmayanti, M.G., Radiman, C.L., 2015. Synthesis and Characterization of Kappa-carrageenan-graft-acrylamide for Enhanced Oil Recovery. Polymer-Plastics Technology and Engineering, Volume 54(3), pp. 259–264

Ellis, A., Keppeler, S., Jacquier, J.C., 2009. Responsiveness of κ-carrageenan MICROGELs to Cationic Surfactants and Neutral Salts. Carbohydrate Polymer, Volume 78, pp. 384–388

Espinosa-Ozib, A., Ramirez-Gilly, M., Tecante, A., 2012. Viscoelastic Behavior and Microstructure of Aqueous Mixtures of Cross-linked Waxy Maize Starch, Whey Protein Isolate and κ-carrageenan. Food Hydrocolloid, Volume 28, pp. 248–257

Ezekwe, N., 2011. Petroleum Reservoir Engineering Practice. Pearson Education Inc., USA

Gaaloul, S., Corredig, M., Turgeon, S.L., 2009. Rheological Study of the Effect of Shearing Process and κ-carrageenan Concentration on the Formation of Whey Protein Microgels at pH 7. Journal of Food Engineering, Volume 95, pp. 254–263

Harrington, J.C., Foegeding, E.A., Mulvihill, D.M., Morris, E.R., 2009. Segregative Interactions and Competitive Binding of Ca2+ in Gelling Mixtures of Whey Protein Isolate with Na+ κ-carrageenan. Food Hydrocolloid, Volume 23, pp. 468–489

Iglauer, S., Wu, Y., Shuler, P., Tang, Y., Goddard III, W.A., 2011. Dilute Iota- and Kappa- carrageenan Solutions with High Viscosities in High Salinity Brines. Journal of Petroleum Science and Engineering, Volume 75, pp. 304–311

Mobarak, N.N., Ramli, N., Ahmad, A., Rahman, M.Y.A., 2012. Chemical Interaction and Conductivity of Carboxymethyl κ-carrageenan based Green Polymer Electrolyte. Solid State Ionics, Volume 224, pp. 51–57

Sen, M., Erboz, E.N., 2010. Determination of Critical Gelation Conditions of κ-carrageenan by Viscosimetric and FT-IR Analyses. Food Research International, Volume 43, pp. 1361–1364

Shanmugan, S., Manavalan, R., Venkappayya, D., Sundaramoorthy, K., Mounissamy, V.M., Hemalatha, S., Ayyappan, T., 2005. Natural Polymers and their Applications. Indian Journal of Natural Products and Resources, Volume 4(6), pp. 478–481

Sheng, J.J., 2011. Modern Chemical Enhanced Oil Recovery Theory and Practice. Elsevier Inc., USA

Zhu, J., Yang, X., Ahmad, I., Li, L., Wang, X., Liu, C., 2008. Rheological Properties of κ-carrageenan and Soybean Glycinin Mixed Gels. Food Research International, Volume 41, pp. 219–228